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Before Pitt – married to Jennifer Aniston from 2000 to 2005 – met Jolie on the set of Mr. and Mrs. Smith (2005), the latter adopted a son, Maddox Jolie-Pitt (22), from Cambodia, and a daughter, Zahara Jolie-Pitt (19), from Ethiopia.
In 2006, the former Hollywood power couple had their first biological daughter, Shiloh, the 18-year-old who in May 2024 filed to have her dad’s name removed from her surname.